Etymology
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vestment (n.)

c. 1300, from Old French vestment (12c., Modern French vêtement), from Latin vestimentum "clothing, clothes," from vestire "to clothe," from PIE *wes- (4) "to clothe" (see wear (v.)). Related: Vestments; vestmental.

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Definitions of vestment

vestment (n.)
gown (especially ceremonial garments) worn by the clergy;
From wordnet.princeton.edu