prefix of reversal, deprivation, or removal (as in unhand, undo, unbutton), Old English on-, un-, from Proto-Germanic *andi- (source also of Old Saxon ant-, Old Norse and-, Dutch ont-, Old High German ant-, German ent-, Gothic and- "against"), from PIE *anti "facing opposite, near, in front of, before, against" (from PIE root *ant- "front, forehead," with derivatives meaning "in front of, before").
More or less confused with un- (1) through similarity in the notions of "negation" and "reversal;" an adjective such as unlocked might represent "not locked" (un- (1)) or the past tense of unlock (un- (2)).
Old English þawian (transitive), from Proto-Germanic *thawon- (source also of Old Norse þeyja, Middle Low German doien, Dutch dooien, Old High German douwen, German tauen "to thaw"), from PIE root *ta- "to melt, dissolve" (source also of Sanskrit toyam "water," Ossetic thayun "to thaw," Welsh tawadd "molten," Doric Greek takein "to melt, waste, be consumed," Old Irish tam "pestilence," Latin tabes "a melting, wasting away, putrefaction," Old Church Slavonic tajati "to melt"). Intransitive sense from early 14c. Related: Thawed; thawing.
<a href="https://www.etymonline.com/word/unthaw">Etymology of unthaw by etymonline</a>
Harper, D. (n.d.). Etymology of unthaw. Online Etymology Dictionary. Retrieved $(datetime), from https://www.etymonline.com/word/unthaw