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unionize (v.)

1841, "make into a union" (transitive), from union + -ize. Sense "form into a trade union" is from 1887. Related: Unionized; unionizing.

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Definitions of unionize from WordNet

unionize (v.)
recruit for a union or organize into a union;
We don't allow people to come into our plant and try to unionize the workers
Synonyms: unionise
unionize (v.)
form or join a union;
The auto workers decided to unionize
Synonyms: unionise / organize / organise
From wordnet.princeton.edu