Etymology
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unacquainted (adj.)

1520s, from un- (1) "not" + past participle of acquaint (v.).

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Definitions of unacquainted

unacquainted (adj.)
not knowledgeable about something specified;
a person unacquainted with our customs
Synonyms: innocent
unacquainted (adj.)
having little or no knowledge of;
unacquainted with city ways
Synonyms: unacquainted with / unfamiliar with
From wordnet.princeton.edu