skull-cap (n.)

"cranium, the bony framework of the head," c. 1200, sculle, probably from Old Norse skalli "a bald head, skull," a general Scandinavian word (compare Swedish skulle, Norwegian skult), itself probably related to Old English scealu "husk" (see shell (n.)).

But early prominence in southwestern texts suggests rather origin from a Dutch or Low German cognate (such as Dutch schol "turf, piece of ice," but the sense of "head bone framework" is wanting). Derivation from Old French escuelle "bowl" seems unlikely on grounds of sound and sense. An Old English word for skull was heafod-bolla. Latin cranium also is glossed at least once in Middle English as braynpanne.

late Old English cæppe "hood, head-covering, cape," a general Germanic borrowing (compare Old Frisian and Middle Dutch kappe, Old High German chappa) from Late Latin cappa "a cape, hooded cloak" (source of Spanish capa, Old North French cape, French chape), a word of uncertain origin. Possibly a shortened from capitulare "headdress," from Latin caput "head" (from PIE root *kaput- "head").

The Late Latin word apparently originally meant "a woman's head-covering," but the sense was transferred to "hood of a cloak," then to "cloak" itself, though the various senses co-existed. Old English took in two forms of the Late Latin word, one meaning "head-covering," the other "ecclesiastical dress" (see cape (n.1)). In most Romance languages, a diminutive of Late Latin cappa has become the usual word for "head-covering" (such as French chapeau).

The meaning "soft, small, close-fitted head covering" in English is from early 13c., originally for women; extended to men late 14c.; extended to cap-like coverings on the ends of anything (as in hubcap) from mid-15c. The meaning "contraceptive device" is by 1916.

The meaning "cap-shaped piece of copper lined with gunpowder and used to ignite a firearm" is by 1825, hence cap-gun (1855); extended to paper strips used in toy pistols by 1872 (cap-pistol is from 1879).

Figurative thinking cap is from 1839 (considering cap is 1650s). Cap and bells (1781) was the insignia of a fool; cap and gown (1732) of a scholar. To set one's cap at or for (1773) means "use measures to gain the regard or affection of," usually in reference to a woman seeking a man's courtship.