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psilocybin (n.)

1958, from Modern Latin psilocybe, name of a Central American species of mushroom, from Greek psilos "bare" (see psilo-) + kybē "head."

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Definitions of psilocybin from WordNet

psilocybin (n.)
a hallucinogenic compound obtained from a mushroom;
Synonyms: psilocin
From wordnet.princeton.edu