Etymology
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postmaster (n.)

1510s, "officer who has charge of a post-station and provides post-horses," from post (n.3) + master (n.). Later "official who has superintendence of a post office." Postmaster general "chief of a postal system" is by 1620s.

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Definitions of postmaster

postmaster (n.)
the person in charge of a post office;
From wordnet.princeton.edu