late Old English ploccian, pluccian "pull off, cull," from West Germanic *plokken (source also of Middle Low German plucken, Middle Dutch plocken, Dutch plukken, Flemish plokken, German pflücken), perhaps from Vulgar Latin *piluccare (source of Old French peluchier, late 12c.; Italian piluccare), a frequentative, ultimately from Latin pilare "pull out hair," from pilus "hair" (see pile (n.3)). But despite the similarities, OED finds difficulties with this and cites gaps in historical evidence. Related: Plucked; plucking.
To pluck a rose, an expression said to be used by women for going to the necessary house, which in the country usually stands in the garden. [F. Grose, "Classical Dictionary of the Vulgar Tongue," 1785]
This euphemistic use is attested from 1610s. To pluck up "summon up" is from c. 1300.