Etymology
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pee (v.)

1788, "to spray with urine" (trans.), euphemistic abbreviation of piss. Meaning "to urinate" is from 1879. Related: Peed; peeing. Noun meaning "act of urination" is attested by 1902; as "urine" by 1961. Reduplicated form pee-pee is attested by 1923.

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Definitions of pee
1
pee (n.)
liquid excretory product;
Synonyms: urine / piss / piddle / weewee / water
pee (n.)
informal terms for urination;
he took a pee
Synonyms: peeing / pissing / piss
2
pee (v.)
eliminate urine;
Synonyms: make / urinate / piddle / puddle / micturate / piss / pee-pee / make water / relieve oneself / take a leak / spend a penny / wee / wee-wee / pass water
From wordnet.princeton.edu