overachiever (n.)

word-forming element meaning variously "above; highest; across; higher in power or authority; too much; above normal; outer; beyond in time, too long," from Old English ofer (from PIE root *uper "over"). Over and its Germanic relations were widely used as prefixes, and sometimes could be used with negative force. This is rare in Modern English, but compare Gothic ufarmunnon "to forget," ufar-swaran "to swear falsely;" Old English ofercræft "fraud."

In some of its uses, moreover, over is a movable element, which can be prefixed at will to almost any verb or adjective of suitable sense, as freely as an adjective can be placed before a substantive or an adverb before an adjective. [OED]

Among the old words not now existing are Old English oferlufu (Middle English oferlufe), literally "over-love," hence "excessive or immoderate love." Over- in Middle English also could carry a sense of "too little, below normal," as in over-lyght "of too little weight" (c. 1400), overlitel "too small" (mid-14c.), oversmall (mid-13c.), overshort, etc.

early 14c., acheven, "to perform, execute, accomplish;" late 14c., "gain as a result of effort," from Old French achever (12c.) "to finish, accomplish, complete," from phrase à chef (venir) "at an end, finished," or Vulgar Latin *accapare, from Late Latin ad caput (venire); both the French and Late Latin phrases meaning literally "to come to a head," from ad "to" (see ad-) + stem of Latin caput "head" (from PIE root *kaput- "head").

The Lat. caput, towards the end of the Empire, and in Merov[ingian] times, took the sense of an end, whence the phrase ad caput venire, in the sense of to come to an end .... Venire ad caput naturally produced the Fr. phrase venir à chef = venir à bout. ... From this chief, O.Fr. form of chef (q.v.) in sense of term, end, comes the Fr. compd. achever = venir à chef, to end, finish. [Auguste Brachet, "An Etymological Dictionary of the French Language," transl. G.W. Kitchin, Oxford, 1878]

Related: Achieved; achieving.