"having the quality of obstructing, serving or intended to hinder, delay, or annoy," 1610s, from Latin obstruct-, past-participle stem of obstruere "to build up, block, block up, build against, stop, bar, hinder" (see obstruction) + -ive.
"action of blocking up a way or passage, act of impeding passage or movement; fact of being obstructed," 1530s, from Latin obstructionem (nominative obstructio) "an obstruction, barrier, a building up," noun of action from past-participle stem of obstruere "build up, block, block up, build against, stop, bar, hinder," from ob "in front of, in the way of" (see ob-) + struere "to pile, build" (from PIE *streu-, extended form of root *stere- "to spread"). Figurative use is by 1650s.
word-forming element making adjectives from verbs, meaning "pertaining to, tending to; doing, serving to do," in some cases from Old French -if, but usually directly from Latin adjectival suffix -ivus (source also of Italian and Spanish -ivo). In some words borrowed from French at an early date it has been reduced to -y (as in hasty, tardy).
<a href="https://www.etymonline.com/word/obstructive">Etymology of obstructive by etymonline</a>
Harper, D. (n.d.). Etymology of obstructive. Online Etymology Dictionary. Retrieved $(datetime), from https://www.etymonline.com/word/obstructive