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matron (n.)

late 14c., matrone, "married woman," usually one of rank or social respectability and mature years (old enough to be the mother of a family, whether actually so or not), from Old French matrone "married woman; elderly lady; patroness; midwife," and directly from Latin mātrona "married woman, wife, matron," from māter (genitive mātris) "mother" (see mother (n.1)).

Also (15c.) "a married female saint." Sense of "female manager of a school, head nurse in a hospital, etc." is recorded by 1550s.

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Definitions of matron from WordNet

matron (n.)
a married woman (usually middle-aged with children) who is staid and dignified;
matron (n.)
a wardress in a prison;
matron (n.)
a woman in charge of nursing in a medical institution;
From wordnet.princeton.edu