leathern (adj.)

Old English leðer (only in compounds) "tanned or otherwise dressed hide or skin of an animal," from Proto-Germanic *lethran (source also of Old Norse leðr, Old Frisian lether, Old Saxon lethar, Middle Dutch, Dutch leder, Old High German ledar, German Leder), from PIE *letro- "leather" (source also of Old Irish lethar, Welsh lledr, Breton lezr). As an adjective from early 14c.; it acquired a secondary sense of "sado-masochistic" 1980s, having achieved that status in homosexual jargon in the 1970s.

In commercial and popular usage leather does not include skins dressed with the hair or fur on: such skins are usually distinguished by compounding the word skin with the name of the animal from which they are taken: as sealskin, bearskin, otter skin, etc. In the untanned state skins valued for their fur, hair, or wool and destined to be tawed and dressed for furriers' and analogous uses, are called pelts or peltry. [Century Dictionary, 1900]

suffix added to nouns to produce adjectives meaning "made of, of the nature of" (such as golden, oaken, woolen), corresponding to Latin -anus, -inus, Greek -inos; from Proto-Germanic *-ina- (from PIE *-no-, adjectival suffix).

Common in Old, Middle, and early Modern English: e.g. fyren "on fire; made of fire," rosen "made or consisting of roses," hunden "of dogs, canine," beanen "of beans," baken "baked," breaden "of bread;" Wyclif has reeden made of or consisting of reeds." The few surviving instances are largely discarded in everyday use, and the simple form of the noun doubles as adjective (gold ring, wool sweater). Some are used in special contexts (brazen, wooden).