Words related to impure
In Old French and Middle English often en-, but most of these forms have not survived in Modern English, and the few that do (enemy, for instance) no longer are felt as negative. The rule of thumb in English has been to use in- with obviously Latin elements, un- with native or nativized ones.
mid-13c., of gold, "unalloyed;" c. 1300 "unmixed, unadulterated; homogeneous," also "total, complete, absolute; bare, mere," also "sexually pure, virgin, chaste" (late 12c. as a surname, and Old English had purlamb "lamb without a blemish"), from Old French pur "pure, simple, absolute, unalloyed," figuratively "simple, sheer, mere" (12c.), from Latin purus "clean, clear; unmixed; unadorned; chaste, undefiled."
This is conjectured to be from PIE root *peue- "to purify, cleanse" (source also of Latin putus "clear, pure;" Sanskrit pavate "purifies, cleanses," putah "pure;" Middle Irish ur "fresh, new;" Old High German fowen "to sift").
It replaced Old English hlutor. The meaning "free from moral corruption" is recorded from mid-14c. In reference to bloodlines, attested from late 15c. In music, "mathematically perfect," by 1872.