Etymology
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immediately (adv.)

"without intervening time or space, directly," early 15c., from immediate + -ly (2).

updated on October 19, 2015

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Definitions of immediately from WordNet

immediately (adv.)
without delay or hesitation; with no time intervening;
he answered immediately
Synonyms: instantly / straightaway / straight off / directly / now / right away / at once / forthwith / like a shot
immediately (adv.)
near or close by;
he passed immediately behind her
immediately (adv.)
bearing an immediate relation;
this immediately concerns your future
From wordnet.princeton.edu, not affiliated with etymonline.