Old English he, pronoun of the third person (see paradigm of Old English third person pronoun below), from Proto-Germanic *hi- (source also of Old Saxon, Old Frisian, Middle Dutch he, hi, Dutch hy, Old High German he), from PIE *ki-, variant of root *ko-, the "this, here" (as opposed to "that, there") root, and thus the source of the third person pronouns in Old English. The feminine, hio, was replaced in early Middle English by forms from other stems (see she), while the h- wore off Old English neuter hit to make modern it. The Proto-Germanic root also is the source of the first element in German heute "today," literally "the day" (compare Old English heodæg).

The paradigm in Old English was: MASCULINE SINGULAR: he (nominative), hine (accusative), his (genitive), him (dative); FEMININE SINGULAR: heo, hio (nom.), hie, hi (acc.), hire (gen. and dat.); NEUTER SINGULAR: hit (nom. and acc.), his (gen.), him (dat.); PLURAL: (all genders) hie, hi (nom. and acc.), hira, heora (gen.), him, heom (dat.).

Pleonastic use with the noun ("Mistah Kurtz, he dead") is attested from late Old English. With animal words, meaning "male" (he-goat, etc.) from c. 1300.

Old English him selfum, from dative/accusative personal pronoun him + self, here used as an inflected adjective.

Old English hine, accusative of he; replaced by dative him in early Middle English. Cognate with German ihn. It is said to survive somewhat in southwest English and Kentish dialect.

Proto-Indo-European root, the stem of demonstrative pronoun meaning "this."

It forms all or part of: cis-; et cetera; harass; he; hence; her; here; him; his; hither; it.

It is the hypothetical source of/evidence for its existence is provided by:  Greek ekeinos "that person;" Latin cis "on this side," citra (adv.) "on this side;" Old Church Slavonic si, Lithuanian is, Hittite ki "this;" Old English hider, Gothic hidre "hither."