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hierarch (n.)

"one who rules in holy things," 1570s, from Medieval Latin hierarcha, from Greek hierarkhia, from hierarkhes "leader of sacred rites, high priest" (see hierarchy).

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Definitions of hierarch from WordNet

hierarch (n.)
a person who holds a high position in a hierarchy;
hierarch (n.)
a senior clergyman and dignitary;
Synonyms: archpriest / high priest / prelate / primate
From wordnet.princeton.edu