Etymology
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face (n.)

c. 1300, "the human face, a face; facial appearance or expression; likeness, image," from Old French face "face, countenance, look, appearance" (12c.), from Vulgar Latin *facia (source also of Italian faccia), from Latin facies "appearance, form, figure," and secondarily "visage, countenance," which probably is literally "form imposed on something" and related to facere "to make" (from PIE root *dhe- "to set, put").

Replaced Old English andwlita "face, countenance" (from root of wlitan "to see, look") and ansyn, ansien, the usual word (from the root of seon "see"). Words for "face" in Indo-European commonly are based on the notion of "appearance, look," and are mostly derivatives from verbs for "to see, look" (as with the Old English words, Greek prosopon, literally "toward-look," Lithuanian veidas, from root *weid- "to see," etc.). But in some cases, as here, the word for "face" means "form, shape." In French, the use of face for "front of the head" was given up 17c. and replaced by visage (older vis), from Latin visus "sight."

From late 14c. as "outward appearance (as contrasted to some other reality);" also from late 14c. as "forward part or front of anything;" also "surface (of the earth or sea), extent (of a city)." Typographical sense of "part of the type which forms the letter" is from 1680s.

Whan she cometh hoom, she raumpeth in my face And crieth 'false coward.' [Chaucer, "Monk's Tale"]

Face to face is from mid-14c. Face time is attested from 1990. To lose face "lose prestige" (1835), is from Chinese tu lien; hence also save face (1898; see save). To show (one's) face "make or put in an appearance" is from mid-14c. (shewen the face). To make a face "change the appearance of the face in disgust, mockery, etc." is from 1560s. Two faces under one hood as a figure of duplicity is attested from mid-15c.

Two fases in a hode is neuer to tryst. ["Awake lordes," 1460]

face (v.)

"confront with assurance; show a bold face," mid-15c., from face (n.). From c. 1400 as "deface, disfigure." Meaning "to cover with something in front" is from 1560s; that of "turn the face toward" is from 1630s; meaning "be on the opposite page to" is from 1766. Intransitive sense "to turn the face" (especially in military tactics) is from 1630s. Related: Faced; facing. To face the music (1850, in U.S. Congressional debates) probably is theatrical rather than a reference to cavalry horses.

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Definitions of face
1
face (n.)
the front of the human head from the forehead to the chin and ear to ear;
I wish I had seen the look on his face when he got the news
he washed his face
Synonyms: human face
face (n.)
the feelings expressed on a person's face;
an angry face
Synonyms: expression / look / aspect / facial expression
face (n.)
the general outward appearance of something;
the face of the city is changing
face (n.)
the striking or working surface of an implement;
face (n.)
a part of a person that is used to refer to a person;
he looked out at a roomful of faces
when he returned to work he met many new faces
face (n.)
a surface forming part of the outside of an object;
dew dripped from the face of the leaf
they travelled across the face of the continent
Synonyms: side
face (n.)
the part of an animal corresponding to the human face;
face (n.)
the side upon which the use of a thing depends (usually the most prominent surface of an object);
he dealt the cards face down
face (n.)
a contorted facial expression;
Synonyms: grimace
face (n.)
a specific size and style of type within a type family;
Synonyms: font / fount / typeface / case
face (n.)
status in the eyes of others;
he lost face
face (n.)
impudent aggressiveness;
Synonyms: boldness / nerve / brass / cheek
face (n.)
a vertical surface of a building or cliff;
2
face (v.)
deal with (something unpleasant) head on;
He faced the terrible consequences of his mistakes
Synonyms: confront / face up
face (v.)
oppose, as in hostility or a competition;
Jackson faced Smith in the boxing ring
Synonyms: confront
face (v.)
be oriented in a certain direction, often with respect to another reference point; be opposite to;
The building faces the park
Synonyms: front / look
face (v.)
be opposite;
the two sofas face each other
face (v.)
turn so as to face; turn the face in a certain direction;
Turn and face your partner now
face (v.)
present somebody with something, usually to accuse or criticize;
An enormous dilemma faces us
He was faced with all the evidence and could no longer deny his actions
Synonyms: confront / present
face (v.)
turn so as to expose the face;
face a playing card
face (v.)
line the edge (of a garment) with a different material;
face the lapels of the jacket
face (v.)
cover the front or surface of;
The building was faced with beautiful stones
From wordnet.princeton.edu