also faceoff, 1886 in sports (hockey, etc., originally lacrosse), from verbal phrase in a sports sense, attested from 1867 (see face (v.) + off (adv.)); the off perhaps is based on stand-off or similar constructions.
"confront with assurance; show a bold face," mid-15c., from face (n.). From c. 1400 as "deface, disfigure." Meaning "to cover with something in front" is from 1560s; that of "turn the face toward" is from 1630s; meaning "be on the opposite page to" is from 1766. Intransitive sense "to turn the face" (especially in military tactics) is from 1630s. Related: Faced; facing. To face the music (1850, in U.S. Congressional debates) probably is theatrical rather than a reference to cavalry horses.
by c. 1200 as an emphatic form of Old English of (see of), employed in the adverbial use of that word. The prepositional meaning "away from" and the adjectival sense of "farther" were not firmly fixed in this variant until 17c., but once they were they left the original of with the transferred and weakened senses of the word. Meaning "not working" is from 1861.
Off the cuff "extemporaneously, without preparation" (1938) is from the notion of speaking from notes written in haste on one's shirt cuffs. In reference to clothing, off the rack (adj.) "not tailored, not made to individual requirements, ready-made" is by 1963, on the notion of buying it from the rack of a clothing store; off the record "not to be publicly disclosed" is from 1933; off the wall "crazy" is 1968, probably from the notion of a lunatic "bouncing off the walls" or else in reference to carom shots in squash, handball, etc.