especial (adj.)

late 14c., in logic, "a class of individuals or things," from Latin species "a particular sort, kind, or type" (opposed to genus), originally "a sight, look, view; outward appearance, shape, form," a derivative of specere "to look at, to see, behold" (from PIE root *spek- "to observe"). In English it is attested from 1550s as "appearance, outward form."

Latin species "a sight; outward appearance" had many extended senses, including "a spectacle; a mental appearance, an idea or notion;" also "semblance, pretext; manner, fashion; display, beauty; a likeness or statue; reputation, honor." Typically it was used in passive senses. Also compare spice (n.).

In Late Latin, in logic and legal language, it acquired the meaning "a special case," especially (as a translation of Greek eidos) "a class included under a higher class; a kind; a sort; a number of individuals having common characteristics peculiar to them." The notion (as Lewis & Short puts it) is "The particular thing among many to which the looks are turned."

The English word is attested from 1560s as "a distinct class (of something) based on common characteristics." The specific use in biological sciences in reference to groups of living things recognizably distinct from all others by their inherited characteristics is from c. 1600. Endangered species is attested by 1964.

the later Romans evidently found words beginning in sc-, sp-, st- difficult or unpleasant to pronounce; in Late Latin forms begin to emerge in i- (such as ispatium, ispiritu), and from 5c. this shifted to e-. The development was carried into the Romanic languages, especially Old French, and the French words were modified further after 15c. by natural loss of -s- (the suppression being marked by an acute accent on the e-), while in other cases the word was formally corrected back to the Latin spelling (for example spécial). Hence French état for Old French estat for Latin status, etc. It also affected Romanic borrowings from Germanic (such as espy, eschew).

A different e- is a reduced form of Latin ex- before consonants (see ex-), and the e- in enough is an unfelt survival of an Old English alternative form of ge-.