in grammar, "the arrangement of repeated, parallel, or contrasted words or phrases in pairs with inversion of word order," 1850, Latinized from Greek khiasmos "a placing crosswise, diagonal arrangement" (see chi).
22nd letter of the Greek alphabet, representing a -kh- sound (see ch). The letter is shaped like an X, and so the Greek letter name was used figuratively to signify such a shape or arrangement (as in khiasma "two things placed crosswise;" khiastos "arranged diagonally; marked with an X;" khiazein "to mark with an 'X', to write the letter 'X'"). Some dialects used chi to represent the -ks- sound properly belonging to xi; Latin picked this up and the sound value of chi in Latin-derived alphabets is now that of English X.
Middle English -ik, -ick, word-forming element making adjectives, "having to do with, having the nature of, being, made of, caused by, similar to," from French -ique and directly from Latin -icus or from cognate Greek -ikos "in the manner of; pertaining to." From PIE adjective suffix *-(i)ko, which also yielded Slavic -isku, adjectival suffix indicating origin, the source of the -sky (Russian -skii) in many surnames. In chemistry, indicating a higher valence than names in -ous (first in benzoic, 1791).
In Middle English and after often spelled -ick, -ike, -ique. Variant forms in -ick (critick, ethick) were common in early Modern English and survived in English dictionaries into early 19c. This spelling was supported by Johnson but opposed by Webster, who prevailed.