chef (n.)

c. 1300, "head, leader, captain; the principal or most important part of anything;" from Old French chief "leader, ruler, head" of something, "capital city" (10c., Modern French chef), from Vulgar Latin *capum, from Latin caput "head," also "leader, chief person; summit; capital city" (from PIE root *kaput- "head").

The meaning "head of a clan" is attested from 1570s; it was later extended to headmen of Native American tribes (by 1713; William Penn, 1680s, called them kings). Commander-in-chief is attested from 1660s.

Proto-Indo-European root meaning "head."

It forms all or part of: achieve; behead; biceps; cabbage; cabochon; caddie; cadet; cap; cap-a-pie; cape (n.1) "garment;" cape (n.2) "promontory;" capital (adj.); capital (n.3) "head of a column or pillar;" capitate; capitation; capitulate; capitulation; capitulum; capo (n.1) "leader of a Mafia family;" capo (n.2) "pitch-altering device for a stringed instrument;" caprice; capsize; captain; cattle; caudillo; chapter; chef; chief; chieftain; corporal (n.); decapitate; decapitation; forehead; head; hetman; kaput; kerchief; mischief; occipital; precipice; precipitate; precipitation; recapitulate; recapitulation; sinciput; triceps.

It is the hypothetical source of/evidence for its existence is provided by: Sanskrit kaput-; Latin caput "head;" Old English heafod, German Haupt, Gothic haubiþ "head."

early 19c., from French sous, from Old French soz (10c.), from Latin subtus "under, below" (see sub-) + chef.