city of ancient Attica, capital of modern Greece, from Greek Athenai (plural because the city had several distinct parts), traditionally derived from Athena, but probably assimilated from a lost name in a pre-Hellenic language.
variant of suffix -an (q.v.), with connective -i-. From Latin -ianus, in which the -i- originally was from the stem of the word being attached but later came to be felt as connective. In Middle English frequently it was -ien, via French.
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Definitions of Athenian from WordNet
a resident of Athens;
of or relating to or characteristic of Athens or its inhabitants;