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archduchess (n.)

1610s, modeled on French archiduchesse; see arch- "chief" + duchess. In later use generally "a princess of the reigning family of Austria," translating German Erzherzogin. Compare archduke, which is the masc. form.

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Definitions of archduchess from WordNet

archduchess (n.)
a wife or widow of an archduke or a princess of the former ruling house of Austria;
From wordnet.princeton.edu