form of Latin ad- in compounds with words or stems beginning in -p-; see ad-. In Old French reduced to a-, but scribal re-doubling of ap- to app- in imitation of Latin began 14c. in France, 15c. in England, and was extended to some compounds formed in Old French or Middle English that never had a Latin original (appoint, appall).
In words from Greek, ap- is the form of apo before a vowel (see apo-).