Etymology
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annex (v.)

late 14c., "to connect with," from Old French annexer "to join, attach" (13c.), from Medieval Latin annexare, frequentative of Latin annecetere "to bind to," from ad "to" (see ad-) + nectere "to tie, bind" (from PIE root *ned- "to bind, tie"). Usually meaning "to join in a subordinate capacity," but that notion is not in the etymology. Of nations or territories, c. 1400. Related: Annexed; annexing.

annex (n.)

1540s, "an adjunct, accessory," from French annexe "that which is joined" (13c.), from annexer "to join" (see annex (v.)). Meaning "supplementary building" is from 1861.

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Definitions of annex
1
annex (v.)
take (territory) as if by conquest;
Hitler annexed Lithuania
annex (v.)
attach to;
2
annex (n.)
an addition that extends a main building;
Synonyms: annexe / extension / wing
From wordnet.princeton.edu