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Serb (n.)

1813, but in reference to the Wends; 1861 as "native of Serbia," from Serbian Srb, perhaps from a root meaning "man." Serbian is attested from 1848 as a noun, 1876 as an adjective. More common in 19c. was Servian.

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Definitions of Serb from WordNet

Serb (n.)
a member of a Slavic people who settled in Serbia and neighboring areas in the 6th and 7th centuries;
Synonyms: Serbian
From wordnet.princeton.edu