Etymology
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Serb (n.)

1786, but in reference to the Wends; by 1844 as "native of Serbia," from Serbian Srb, perhaps from a root meaning "man." Serbian is attested from 1833 as an adjective, 1839 as a noun. More common in 19c. was Servian.

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Definitions of Serb

Serb (n.)
a member of a Slavic people who settled in Serbia and neighboring areas in the 6th and 7th centuries;
Synonyms: Serbian
From wordnet.princeton.edu