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Chile

South American country, probably named from a local native word subsequently confused with Mexican Spanish chile "chili pepper" (see chili). Suggestions are that the native word means "land's end" or else "cold, winter" which would make a coincidental convergence with English chilly. Related: Chilean. In 19c., often Chili, Chilian.

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Definitions of Chile from WordNet
1
chile (n.)
very hot and finely tapering pepper of special pungency;
Synonyms: chili / chili pepper / chilli / chilly
2
Chile (n.)
a republic in southern South America on the western slopes of the Andes on the south Pacific coast;
Synonyms: Republic of Chile
From wordnet.princeton.edu