Etymology
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pleio- 

also pleo-, word-forming element meaning "more," from Greek pleiōn "larger, greater in quantity, the more part, very many" (comparative of polys "much"), from PIE *ple- (source also of Latin plere "to fill," plebes, "the populace, the common people;" Greek plēthein "be full," plērēs "full"), possibly a variant of root *pele- (1) "to fill."

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poly- 

word-forming element meaning "many, much, multi-, one or more," from Greek polys "much" (plural polloi), from PIE root *pele- (1) "to fill," with derivatives referring to multitudinousness or abundance. Equivalent to Latin multi-, it is properly used in compounds only with words of Greek origin. In chemical names, usually indicating a compound with a large number of atoms or molecules of the same kind (such as polymer).

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