Old English cealc "chalk, soft white limestone; lime, plaster; pebble," a West Germanic borrowing from Latin calx (2) "limestone, lime (crushed limestone), small stone," from Greek khalix "small pebble," which many trace to a PIE root for "split, break up."
Cognate words in most Germanic languages still have the "limestone" sense, but in English transferred chalk to the opaque, white, soft limestone found abundantly in the south of the island. The modern spelling is from early 14c. The Latin word for "chalk" was creta, which also is of unknown origin. With many figurative or extended senses due to the use of chalk marks to keep tracks of credit for drinks in taverns and taprooms, or to keep the score in games.
metallic element, coined 1808 by English chemist Sir Humphry Davy, who first succeeded in isolating it, from Latin calx (genitive calcis) "limestone" (see chalk (n.)) + metallic element ending -ium. Related: Calcic.