also faceoff, 1886 in sports (hockey, etc., originally lacrosse), from verbal phrase in a sports sense, attested from 1867 (see face (v.) + off (adv.)); the off perhaps is based on stand-off or similar constructions.
1858, "defective or inferior because not of a natural or proper color," from off (prep.) + color (n.); originally used of gems; figurative extension to "not of the proper character, of questionable taste, risqué" is American English, 1867.
by 1911, of music or singing, "not having the correct tone or pitch, out of tune," from off (prep.) + musical sense of key (n.1). Figurative sense "not in accordance with what is appropriate in the circumstances" is by 1943.