early 14c., from un- (2) "reverse of" + cover (v.). Earliest use is figurative; literal sense is attested from late 14c. Related: Uncovered; uncovering.
1530s, "to unload" (transitive), from un- (2) "reverse of" + burden (v.). Similar formation in German entbürden. Reflexive sense is recorded from 1580s. Related: Unburdened; unburdening.
1580s in figurative sense, c. 1600 in literal sense (transitive and intransitive), from un- (2) "reverse, opposite of" + mask (v.). Related: Unmasked; unmasking.