Etymology
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walk-on (n.)
"minor non-speaking role," 1902, theatrical slang, from the verbal phrase walk on, attested in theater jargon by 1897 with a sense "appear in crowd scenes," from walk (v.) + on (adv.). Meaning "actor who has such a part" is attested from 1946. The sports team sense is recorded from 1974.
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walk (v.)

"travel on foot," c. 1200, a merger of two verbs, 1. Old English wealcan "to toss, roll, move round" (past tense weolc, past participle wealcen), and 2. wealcian "to roll up, curl," from Proto-Germanic *welk- (source also of Old Norse valka "to drag about," Danish valke "to full" (cloth), Middle Dutch walken "to knead, press, full" (cloth), Old High German walchan "to knead," German walken "to full"), perhaps ultimately from PIE root *wel- (3) "to turn, revolve."

The shift in sense is perhaps from a colloquial use of the Old English word or via the sense of "to full cloth" (by treading on it), though this sense does not appear until after the change in meaning. In 13c. it is used of snakes and the passage of time, and in 15c. of wheeled carts. "Rarely is there so specific a word as NE walk, clearly distinguished from both go and run" [Buck]. Meaning "to go away" is recorded from mid-15c. Transitive meaning "to exercise a dog (or horse)" is from late 15c.; meaning "to escort (someone) in a walk" is from 1620s. Meaning "move (a heavy object) by turning and shoving it in a manner suggesting walking" is by 1890. To walk it off, of an injury, etc., is from 1741. Related: Walked; walking.

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walk (n.)

c. 1200, "a tossing, rolling;" mid-13c., "an act of walking, a going on foot;" late 14c., "a stroll," also "a path, a walkway;" from walk (v.). The meaning "broad path in a garden" is from 1530s. Meaning "particular manner of walking" is from 1650s. Meaning "manner of action, way of living" is from 1580s; hence walk of life (1733). Meaning "range or sphere of activity" is from 1759. Sports sense of "base on balls" is recorded from 1905; to win in a walk (1854) is from horse racing (see walk-over). As a type of sponsored group trek as a fund-raising event, by 1971 (walk-a-thon is from 1963).

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air (n.3)
"melody, tune, connected rhythmic succession of distinct musical sounds," 1580s, nativized from Italian aria (see aria), perhaps via French.
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on- 

the preposition and adverb on used as a prefix; Old English on-, an-.

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-on 
subatomic particle suffix, from ion.
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on (prep., adv.)

"in a position above and in contact with; in such a position as to be supported by;" also noting the goal to which some action is or has been directed; "about, concerning, regarding; in a position to cover;" as an adverb, "in or into a position in contact with and supported by the top or upper part of something; in or into place; in place for use or action; into movement or action; in operation," Old English on, unstressed variant of an "in, on, into," from Proto-Germanic *ana "on" (source also of Dutch aan, German an, Gothic ana "on, upon"), from PIE root *an- (1) "on" (source also of Avestan ana "on," Greek ana "on, upon," Latin an-, Old Church Slavonic na, Lithuanian nuo "down from").

Also used in Old English in many places where we now would use in. From 16c.-18c. (and still in northern England dialect) often reduced to o'. Phrase on to "aware" is from 1877.

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air (n.1)

c. 1300, "invisible gases that surround the earth," from Old French air "atmosphere, breeze, weather" (12c.), from Latin aer "air, lower atmosphere, sky," from Greek aēr (genitive aeros) "mist, haze, clouds," later "atmosphere" (perhaps related to aenai "to blow, breathe"), which is of unknown origin. It is possibly from a PIE *awer- and thus related to aeirein "to raise" and arteria "windpipe, artery" (see aorta) on notion of "lifting, suspended, that which rises," but this has phonetic difficulties.

In Homer mostly "thick air, mist;" later "air" as one of the four elements. Words for "air" in Indo-European languages tend to be associated with wind, brightness, sky. In English, air replaced native lyft, luft (see loft (n.)). In old chemistry, air (with a qualifying adjective) was used of any gas.

To be in the air "in general awareness" is from 1875; up in the air "uncertain, doubtful" is from 1752. To build castles in the air "entertain visionary schemes that have no practical foundation" is from 1590s (in 17c. English had airmonger "one preoccupied with visionary projects"). Broadcasting sense (as in on the air, airplay) first recorded 1927. To give (someone) the air "dismiss" is from 1900. Air pollution is attested by 1870. Air guitar is by 1983. Air traffic controller is from 1956.

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air (n.2)
1590s, "manner, appearance" (as in an air of mystery); 1650s, "assumed manner, affected appearance" (especially in phrase put on airs, 1781), from French air "look, appearance, mien, bearing, tone" (Old French aire "reality, essence, nature, descent, extraction" (12c.); compare debonair), which is perhaps from Latin ager "place, field, productive land" (from PIE root *agro- "field") on notion of "place of origin."

But some French sources connect this Old French word with the source of air (n.1), and it also is possible these senses in English developed from or were influenced by air (n.1); compare sense development of atmosphere and Latin spiritus "breath, breeze," also "high spirit, pride," and the extended senses of anima.
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air (v.)
1520s, "expose to open air," 1520s, from air (n.1). Figurative sense of "expose ostentatiously, make public" is from 1610s of objects, 1862 of opinions, grievances, etc. Meaning "to broadcast" (originally on radio) is from 1933. Related: Aired; airing.
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