"This Text holdeth their noses so hard to the grindstone, that it clean disfigureth their Faces." [Frith, "Mirror to know Thyself," 1532]The main modern (reflective) sense of "work hard" is from 1828.
"To be fashionable nowadays we must 'brunch'. Truly an excellent portmanteau word, introduced, by the way, last year, by Mr. Guy Beringer, in the now defunct Hunter's Weekly, and indicating a combined breakfast and lunch." ["Punch," Aug. 1, 1896]