The name acetylene is an unfortunate one as the hydrocarbon is not directly related to the modern acetyl radical and the molecule ... contains a triple bond, not a double bond which the suffix -ene (q.v.) implies. [Flood, "Origins of Chemical Names," 1963]
The Lat. caput, towards the end of the Empire, and in Merov[ingian] times, took the sense of an end, whence the phrase ad caput venire, in the sense of to come to an end .... Venire ad caput naturally produced the Fr. phrase venir à chef = venir à bout. ... From this chief, O.Fr. form of chef (q.v.) in sense of term, end, comes the Fr. compd. achever = venir à chef, to end, finish. [Auguste Brachet, "An Etymological Dictionary of the French Language," transl. G.W. Kitchin, Oxford, 1878]Related: Achieved; achieving.