The substance formed, for example, by the action of acetic acid (vinegar) on lead was described in the 18th century as plumbum acetatum, i.e. acetated lead. Acetatum was then taken as a noun meaning "the acetated (product)," i.e. acetate. [W.E. Flood, "The Origins of Chemical Names," London, 1963]
[I]t naturally happened that all these a- prefixes were at length confusedly lumped together in idea, and the resultant a- looked upon as vaguely intensive, rhetorical, euphonic, or even archaic, and wholly otiose. [OED]